Precipitated Barium Sulfate For Battery

Synthesis Process of Precipitated Barium Sulfate


High purity and low Fe content, suitable for battery use.


Product Details

Product Features:

Particle size distribution is narrow.

Less impurity.

Excellent dispersibility.


Natural Barium Sulfate Technical Data:

Barium sulphate content (Baso4)%98
Whiteness%≥96
Water soluble content %≤0.15
Fe Content % ≤0.0015
Cl Content % ≤0.04
PH Value6.5-7.5
Oil absorption  g/100g15-20
Mean Particle Size (D50)1.2um
Residue    (45μm) %0.01
Particle size less than 10μm %99
Particle size less than 5μm %95
Particle size less than 2μm %70


As battery technology evolves, material scientists and manufacturers are increasingly turning to precipitated barium sulfate (BaSO₄) as a functional filler in battery separators, electrolyte composites, and polymeric casings. Its chemical stability, high density, electrical insulation, and particle uniformity make it a valuable additive in both lead-acid and lithium-ion battery components.

This article provides a technically detailed, SEO-optimized, and regulation-aware guide on the use of precipitated barium sulfate for battery applications. We will explore its manufacturing, structural properties, compliance requirements, use cases, and operational considerations—followed by FAQs and a professional call to action.


What Is Precipitated Barium Sulfate?

Precipitated barium sulfate, often referred to as blanc fixe, is a synthetically produced, ultra-pure form of BaSO₄. Unlike naturally occurring barite, precipitated BaSO₄ is manufactured via a controlled chemical reaction that ensures consistent morphology, narrow particle size distribution, and low impurity levels.

Synthesis Reaction (Typical):

BaCl2+Na2SO4BaSO4+2NaClBaCl_2 + Na_2SO_4 → BaSO_4 ↓ + 2NaCl

This process results in a white, chemically inert, non-toxic powder, widely used in technical applications, including batteries.


Why Use Precipitated Barium Sulfate in Batteries?

PropertyBenefit in Battery Systems
High Specific Gravity (4.3–4.5)Enhances density of battery pastes and structural fillers
Chemical InertnessStable against acid electrolytes and reactive battery compounds
Excellent DispersibilityForms homogeneous composite mixtures in separators or coatings
Electrical InsulationPrevents short-circuiting and improves dielectric performance
Narrow Particle Size (D50 0.5–1.5μm)Ensures uniform coating and minimized voids in polymers

Applications in Battery Technologies

1. Lead-Acid Battery Paste

  • Acts as an inert filler in negative and positive plates

  • Improves mechanical integrity, reduces plate expansion

  • Enhances weight balance without compromising electrical performance

2. Lithium-ion Battery Separators

  • Fused into polyolefin separators (e.g., PE/PP) to enhance:

    • Thermal shutdown performance

    • Porosity and dimensional stability

    • Electrolyte wetting behavior

3. Polymer Matrix Electrolytes

  • Used in solid or gel electrolytes to:

    • Stabilize polymer crystallinity

    • Increase dielectric constant

    • Provide barrier properties against dendrite growth

4. Battery Housing and Encapsulation

  • Added to battery casing polymers (e.g., ABS, PP) to improve:

    • Flame retardancy

    • UV resistance

    • Weight and rigidity balance


Technical Specifications (Battery-Grade)

PropertyValue RangeMethod / Standard
BaSO₄ Purity≥ 98.5%ISO 3262-2 / GB/T 2899
Specific Gravity4.3–4.5ASTM D153 / ISO 787-10
D50 Particle Size0.5–1.5 μmLaser Diffraction (ISO 13320)
Whiteness (ISO)≥ 96ISO 2470
Oil Absorption≤ 10 g/100gISO 787-5
Moisture Content≤ 0.2%ISO 787-2
pH (10% slurry)6.5–8.5ISO 787-9
Surface Treatment (Optional)Stearic acid, siliconeManufacturer-specified

Compliance and Safety Considerations

Regulation / ComplianceRelevance to Battery Industry
REACH (EC No. 1907/2006)Compliant and exempted as an inorganic mineral
RoHS DirectiveFree of Pb, Cd, Hg, Cr⁶⁺, PBB, PBDE
UN Manual of Tests and CriteriaNon-hazardous material for transport and storage
NIOSH/OSHA GuidelinesDust control required during handling
ISO 9001 / ISO 14001Most battery-grade BaSO₄ is certified for quality and environment management
Health & Safety: Though BaSO₄ is non-toxic and insoluble, inhalation of fine dust should be minimized using PPE and proper ventilation systems in production lines.

Manufacturing and Quality Control

  • Raw Materials: High-purity BaCO₃ or BaCl₂ + Na₂SO₄

  • Reactor Design: Precise pH, agitation speed, and temperature control

  • Filtration & Washing: Removes NaCl and soluble impurities

  • Drying: Conducted below 120°C to prevent agglomeration

  • Milling & Classification: Jet milling or air classification to D50 < 1.0μm

  • Surface Treatment (if needed): Improves dispersion in polymers or electrolyte matrices


Frequently Asked Questions (FAQs)

❓ Can precipitated barium sulfate improve battery lifespan?

Yes. Its chemical stability and role in reinforcing physical components (e.g., separators, casings) reduce degradation and increase thermal safety margins.

❓ How is it different from natural barite?

Precipitated BaSO₄ is synthetic, ultra-pure, and finer in particle size—tailored for sensitive applications like batteries and medical use, whereas natural barite may contain impurities.

❓ Does it affect battery capacity?

It does not directly contribute to energy storage but plays a functional role in structure, safety, and stability—supporting higher cycle life and system durability.

❓ Is it compatible with lithium-metal and solid-state systems?

Yes. In solid polymer electrolytes or ceramic separators, it acts as a non-conductive barrier and electrolyte stabilizer.


Summary: Why Choose Precipitated BaSO₄ for Batteries?

BenefitValue Delivered
High purity & insulationPrevents ionic leakage and electrical shorts
Thermochemical stabilityWithstands extreme conditions in battery cycles
Fine particle size distributionEnables homogeneous dispersion in polymers and gels
Surface-modifiableCustomization for electrolyte or composite compatibility
Industry-compliantFully meets REACH, RoHS, and transport safety criteria
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